When a concentrated solution of sulphanilic acid and 1-naphthylamine is treated with nitrous acid $(273 \mathrm{~K})$ and acidified with acetic acid, the mass $(\mathrm{g})$ of 0.1 mole of product formed is : (Given molar mass in $\mathrm{g} \mathrm{mol}^{-1} \mathrm{H}: 1, \mathrm{C}: 12, \mathrm{~N}: 14, \mathrm{O}: 16, \mathrm{~S}: 32$ )
Show Hint
- 330
- 33
- 343
- 66
The Correct Option is B
Solution and Explanation
On coupling with 1-naphthylamine (acidified with acetic acid) it gives the azo dye $4\text{-}(4\text{-aminonaphthyl-1-azo})$benzenesulphonic acid, $C_{16}H_{13}N_3O_3S$.
Molar mass $= 16(12) + 13(1) + 3(14) + 3(16) + 32 = 327$ g mol$^{-1}$.
Mass of 0.1 mol $= 32.7 \approx 33$ g: option (2).
Top JEE Main Chemistry Questions
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)- At equilibrium the concentrations of and in a sealed vessel at . What will be for the reaction
- Find out the major products from the following reactions
Cobalt chloride when dissolved in water forms pink colored complex $X$ which has octahedral geometry. This solution on treating with cone $HCl$ forms deep blue complex, $\underline{Y}$ which has a $\underline{Z}$ geometry $X, Y$ and $Z$, respectively, are
- The correct order of atomic radii is:
Top JEE Main Method of Preparation of Diazoniun Salts Questions
- For a sparingly soluble salt \( \text{AB}_2 \), the equilibrium concentrations of \( \text{A}^{2+} \) ions and \( \text{B}^- \) ions are \( 1.2 \times 10^{-4} \, \text{M} \) and \( 0.24 \times 10^{-3} \, \text{M} \), respectively. The solubility product of \( \text{AB}_2 \) is:
- Select the option with correct property -
Top JEE Main Questions
- Two masses $m$ and $\frac{m}{2}$ are connected at the two ends of a massless rigid rod of length $l$. The rod is suspended by a thin wire of torsional constant $k$ at the centre of mass of the rod-mass system(see figure). Because of torsional constant $k$, the restoring torque is $\tau =k\theta$ for angular displacement $\theta$. If the rod is rota ted by $\theta_0$ and released, the tension in it when it passes through its mean position will be:
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)- The value of is
- The number of terms of an is even. The sum of the odd terms is and of the even terms is . The last term exceeds the first by . Then the number of terms in the series is ______.
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,