(i) Heating of Calcium Carbonate:
Observation:
Calcium carbonate decomposes into calcium oxide and carbon dioxide on heating.
Type of Reaction: Thermal decomposition reaction
\[
\text{CaCO}_3 (s) \xrightarrow{\Delta} \text{CaO} (s) + \text{CO}_2 (g)
\]
(ii) Silver Bromide in Sunlight:
Observation:
Silver bromide decomposes into silver and bromine in presence of sunlight, turning grey.
Type of Reaction: Photochemical decomposition reaction
\[
2\text{AgBr} (s) \xrightarrow{\text{Sunlight}} 2\text{Ag} (s) + \text{Br}_2 (g)
\]
(iii) Lead added to Copper (II) Chloride Solution:
Observation:
Lead displaces copper from copper chloride solution, forming lead chloride and copper metal.
Type of Reaction: Displacement reaction
\[
\text{Pb} (s) + \text{CuCl}_2 (aq) \rightarrow \text{PbCl}_2 (s) + \text{Cu} (s)
\]
Conclusion:
These reactions illustrate decomposition (thermal and photochemical) and displacement reactions with balanced chemical equations.