Question:

What are \(X\) and \(Y\) respectively in the following reactions?
\[ X+D_2O\rightarrow C_2D_2+P \] \[ Y+D_2O\rightarrow CD_4+Q \]

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\(\mathrm{CaC_2}\) gives acetylene, while \(\mathrm{Al_4C_3}\) gives methane on reaction with water or heavy water.
Updated On: Jun 15, 2026
  • \(\mathrm{AlCl_3,\ CaCl_2}\)
  • \(\mathrm{Be_2C,\ Al_4C_3}\)
  • \(\mathrm{Al_4C_3,\ CaC_2}\)
  • \(\mathrm{CaC_2,\ Al_4C_3}\)
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The Correct Option is D

Solution and Explanation

Step 1: Identify \(X\).
Calcium carbide reacts with heavy water \(\mathrm{D_2O}\) to form deuterated acetylene \(\mathrm{C_2D_2}\).
\[ \mathrm{CaC_2+2D_2O\rightarrow C_2D_2+Ca(OD)_2} \]
Therefore,
\[ X=\mathrm{CaC_2} \]

Step 2: Identify \(Y\).
Aluminium carbide reacts with heavy water \(\mathrm{D_2O}\) to form deuterated methane \(\mathrm{CD_4}\).
\[ \mathrm{Al_4C_3+12D_2O\rightarrow 3CD_4+4Al(OD)_3} \]
Therefore,
\[ Y=\mathrm{Al_4C_3} \]

Step 3: Final conclusion.
Hence,
\[ \boxed{X=\mathrm{CaC_2},\quad Y=\mathrm{Al_4C_3}} \]
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