Thermal conductivity is a physical property that tells how easily heat can pass through a substance.
In gas analysis, different gases have different thermal conductivities.
A thermal conductivity type gas analyser works on this principle.
Carbon dioxide has thermal conductivity different from that of air or other gases.
So, the amount of \(CO_2\) present in a gas mixture can be estimated by measuring the change in thermal conductivity.
A \(CO_2\) analyser commonly uses this principle.
A polarimeter works on optical rotation.
A spectrometer works on interaction of radiation with matter.
A chromatograph works on separation of components based on distribution between phases.
Therefore, thermal conductivity measurement comprises the working principle of:
\[
CO_2\text{ analyser}.
\]