Step 1: Parametrize the circle.
The circle is \(x^{2}+y^{2}=1\) at \(z=1\). Parametric form (counter-clockwise) is:
\[
x=\cos t,\quad y=\sin t,\quad z=1
\]
But the curve is oriented clockwise, so:
\[
x=\cos t,\quad y=-\sin t
\]
Step 2: Compute differentials.
\[
dx=-\sin t\,dt,\qquad dy=-\cos t\,dt,\qquad dz=0
\]
Step 3: Substitute into the integral.
\[
-3y\,dx + 3x\,dy = -3(-\sin t)(-\sin t) + 3(\cos t)(-\cos t)
\]
\[
= -3(\sin^{2} t + \cos^{2} t) = -3
\]
Step 4: Integrate over \(0\) to \(2\pi\).
\[
\int_{0}^{2\pi} -3\,dt = -6\pi
\]
Step 5: Account for clockwise orientation.
Clockwise reverses the standard orientation:
\[
-(-6\pi) = 6\pi
\]
Conclusion:
The value of the line integral is \(6\pi\).