\( \frac{\pi^2}{16\sqrt{2}} \)
\( I = \int_{0}^{\frac{\pi}{2}} \frac{x \, dx}{\sin^4(2x) + \cos^4(2x)}\)
Let \(2x = t\), then \(dx = \frac{1}{2} dt\), \[ I = \frac{1}{4} \int_{0}^{\pi} \frac{t \, dt}{\sin^4 t + \cos^4 t} \] Using symmetry: \[ I = \frac{1}{4} \int_{0}^{\frac{\pi}{2}} \frac{t + \frac{\pi}{2} - t}{\sin^4 t + \cos^4 t} \, dt \] \[ I = \frac{1}{4} \int_{0}^{\frac{\pi}{2}} \frac{\frac{\pi}{2}}{\sin^4 t + \cos^4 t} \, dt - I \] \[ 2I = \frac{\pi}{8} \int_{0}^{\frac{\pi}{2}} \frac{dt}{\sin^4 t + \cos^4 t} \] Let \(\tan t = y\), then \(\sec^2 t \, dt = dy\): \[ 2I = \frac{\pi}{8} \int_{0}^{\infty} \frac{(1 + y^2) \, dy}{1 + y^4} \] \[ 2I = \frac{\pi}{8} \int_{0}^{\infty} \frac{dy}{y^2 + 1} \] Let \(y = p\), then: \[ I = \frac{\pi}{16} \int_{0}^{\infty} \frac{dp}{p^2 + (\sqrt{2})^2} \] Using the standard integral formula: \[ I = \frac{\pi}{16 \sqrt{2}} \left[ \tan^{-1} \left( \frac{p}{\sqrt{2}} \right) \right]_{0}^{\infty} \] \[ I = \frac{\pi}{16 \sqrt{2}} \cdot \frac{\pi}{2} \] \[ I = \frac{\pi^2}{16 \sqrt{2}} \]
We are asked to evaluate the definite integral \( I = \int_0^{\frac{\pi}{4}} \frac{x \, dx}{\sin^4(2x) + \cos^4(2x)} \).
To solve this integral, we will use the following concepts:
1. King's Property of Definite Integrals: For an integral of the form \( \int_0^a f(x) \, dx \), we have the property:
\[ \int_0^a f(x) \, dx = \int_0^a f(a-x) \, dx \]This property is particularly useful for integrals containing an \( x \) term in the numerator multiplied by a symmetric function.
2. Trigonometric Identities: The denominator can be simplified using the identity:
\[ \sin^4\theta + \cos^4\theta = (\sin^2\theta + \cos^2\theta)^2 - 2\sin^2\theta\cos^2\theta = 1 - 2\left(\frac{\sin(2\theta)}{2}\right)^2 = 1 - \frac{1}{2}\sin^2(2\theta) \]3. Standard Integration Formula:
\[ \int \frac{1}{a^2 + x^2} \, dx = \frac{1}{a}\tan^{-1}\left(\frac{x}{a}\right) + C \]Step 1: Apply the King's Property to the integral.
Let the given integral be \(I\).
\[ I = \int_0^{\frac{\pi}{4}} \frac{x}{\sin^4(2x) + \cos^4(2x)} \, dx \quad \cdots(1) \]Using the property \( \int_0^a f(x) \, dx = \int_0^a f(a-x) \, dx \) with \( a = \frac{\pi}{4} \):
\[ I = \int_0^{\frac{\pi}{4}} \frac{(\frac{\pi}{4} - x)}{\sin^4\left(2\left(\frac{\pi}{4} - x\right)\right) + \cos^4\left(2\left(\frac{\pi}{4} - x\right)\right)} \, dx \]The terms in the denominator become:
\[ \sin\left(2\left(\frac{\pi}{4} - x\right)\right) = \sin\left(\frac{\pi}{2} - 2x\right) = \cos(2x) \] \[ \cos\left(2\left(\frac{\pi}{4} - x\right)\right) = \cos\left(\frac{\pi}{2} - 2x\right) = \sin(2x) \]So the denominator is \( \cos^4(2x) + \sin^4(2x) \), which is the same as the original. Thus, the integral becomes:
\[ I = \int_0^{\frac{\pi}{4}} \frac{\frac{\pi}{4} - x}{\sin^4(2x) + \cos^4(2x)} \, dx \quad \cdots(2) \]Step 2: Add equations (1) and (2) to eliminate \( x \) from the numerator.
\[ 2I = \int_0^{\frac{\pi}{4}} \frac{x + (\frac{\pi}{4} - x)}{\sin^4(2x) + \cos^4(2x)} \, dx \] \[ 2I = \int_0^{\frac{\pi}{4}} \frac{\frac{\pi}{4}}{\sin^4(2x) + \cos^4(2x)} \, dx \] \[ 2I = \frac{\pi}{4} \int_0^{\frac{\pi}{4}} \frac{1}{\sin^4(2x) + \cos^4(2x)} \, dx \]Step 3: Simplify the denominator and evaluate the new integral.
Using the identity \( \sin^4\theta + \cos^4\theta = 1 - \frac{1}{2}\sin^2(2\theta) \), with \( \theta = 2x \):
\[ \sin^4(2x) + \cos^4(2x) = 1 - \frac{1}{2}\sin^2(4x) \]Substituting this into the integral for \(2I\):
\[ 2I = \frac{\pi}{4} \int_0^{\frac{\pi}{4}} \frac{1}{1 - \frac{1}{2}\sin^2(4x)} \, dx = \frac{\pi}{4} \int_0^{\frac{\pi}{4}} \frac{2}{2 - \sin^2(4x)} \, dx \]Let \( u = 4x \), so \( du = 4 \, dx \) or \( dx = \frac{du}{4} \). The limits of integration change from \( x=0 \to u=0 \) and \( x=\frac{\pi}{4} \to u=\pi \).
\[ 2I = \frac{\pi}{2} \int_0^{\pi} \frac{1}{2 - \sin^2(u)} \frac{du}{4} = \frac{\pi}{8} \int_0^{\pi} \frac{1}{2 - \sin^2(u)} \, du \]The integrand \( f(u) = \frac{1}{2 - \sin^2(u)} \) is symmetric about \( u = \frac{\pi}{2} \) (i.e., \( f(\pi - u) = f(u) \)). So, \( \int_0^{\pi} f(u) \, du = 2 \int_0^{\frac{\pi}{2}} f(u) \, du \).
\[ 2I = \frac{\pi}{8} \cdot 2 \int_0^{\frac{\pi}{2}} \frac{1}{2 - \sin^2(u)} \, du = \frac{\pi}{4} \int_0^{\frac{\pi}{2}} \frac{1}{2 - \sin^2(u)} \, du \]Divide the numerator and denominator by \( \cos^2(u) \):
\[ 2I = \frac{\pi}{4} \int_0^{\frac{\pi}{2}} \frac{\sec^2(u)}{2\sec^2(u) - \tan^2(u)} \, du = \frac{\pi}{4} \int_0^{\frac{\pi}{2}} \frac{\sec^2(u)}{2(1 + \tan^2(u)) - \tan^2(u)} \, du \] \[ 2I = \frac{\pi}{4} \int_0^{\frac{\pi}{2}} \frac{\sec^2(u)}{2 + \tan^2(u)} \, du \]Step 4: Perform a second substitution to solve the integral.
Let \( v = \tan(u) \), so \( dv = \sec^2(u) \, du \). The limits change from \( u=0 \to v=0 \) and \( u=\frac{\pi}{2} \to v=\infty \).
\[ 2I = \frac{\pi}{4} \int_0^{\infty} \frac{1}{2 + v^2} \, dv = \frac{\pi}{4} \int_0^{\infty} \frac{1}{(\sqrt{2})^2 + v^2} \, dv \]Using the standard integral \( \int \frac{1}{a^2 + x^2} dx = \frac{1}{a}\tan^{-1}(\frac{x}{a}) \):
\[ 2I = \frac{\pi}{4} \left[ \frac{1}{\sqrt{2}} \tan^{-1}\left(\frac{v}{\sqrt{2}}\right) \right]_0^{\infty} \]Substitute the limits of integration:
\[ 2I = \frac{\pi}{4\sqrt{2}} \left( \lim_{v \to \infty} \tan^{-1}\left(\frac{v}{\sqrt{2}}\right) - \tan^{-1}(0) \right) \] \[ 2I = \frac{\pi}{4\sqrt{2}} \left( \frac{\pi}{2} - 0 \right) = \frac{\pi^2}{8\sqrt{2}} \]Now, solve for \(I\):
\[ I = \frac{\pi^2}{16\sqrt{2}} \]The value of the integral is \( \frac{\pi^2}{16\sqrt{2}} \).
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,