The value of \( 36 \big(4 \cos^2 9^\circ - 1\big) \big(4 \cos^2 27^\circ - 1\big) \big(4 \cos^2 81^\circ - 1\big) \big(4 \cos^2 243^\circ - 1\big) \) is:
Using the trigonometric identity:
\[ 4 \cos^2 \theta - 1 = 4(1 - \sin^2 \theta) - 1 = 3 - 4 \sin^2 \theta = \frac{\sin 3\theta}{\sin \theta}. \]
Substitute this into the given expression:
\[ 36 \big(4 \cos^2 9^\circ - 1\big) \big(4 \cos^2 27^\circ - 1\big) \big(4 \cos^2 81^\circ - 1\big) \big(4 \cos^2 243^\circ - 1\big) \]
\[ = 36 \cdot \frac{\sin 27^\circ}{\sin 9^\circ} \cdot \frac{\sin 81^\circ}{\sin 27^\circ} \cdot \frac{\sin 243^\circ}{\sin 81^\circ} \cdot \frac{\sin 729^\circ}{\sin 243^\circ}. \]
Simplify the product:
\[ = 36 \cdot \frac{\sin 729^\circ}{\sin 9^\circ}. \]
Since \( \sin 729^\circ = \sin 9^\circ \) (as \( 729^\circ \mod 360^\circ = 9^\circ \)):
\[ \frac{\sin 729^\circ}{\sin 9^\circ} = 1. \]
Thus, the value is:
\[ 36 \cdot 1 = 36. \]
A substance 'X' (1.5 g) dissolved in 150 g of a solvent 'Y' (molar mass = 300 g mol$^{-1}$) led to an elevation of the boiling point by 0.5 K. The relative lowering in the vapour pressure of the solvent 'Y' is $____________ \(\times 10^{-2}\). (nearest integer)
[Given : $K_{b}$ of the solvent = 5.0 K kg mol$^{-1}$]
Assume the solution to be dilute and no association or dissociation of X takes place in solution.