The system \( 3x + 5y = 4 \) and \( 6x + ky = 8 \) has infinitely many solutions only when the second equation is just a constant multiple of the first. Notice that the second equation's \( x \)-coefficient (6) and constant term (8) are already exactly double the first equation's \( x \)-coefficient (3) and constant term (4). So for the two equations to be true multiples of each other, the \( y \)-coefficient must double in the same way. Let's check each option against this requirement.
Only \( k = 10 \) makes the second equation an exact multiple of the first, so only then do the equations represent the same line.
Therefore, the correct answer is \( k = 10 \).