Concept:
In material stress–strain behavior, the relationship between stress ($\sigma$) and strain ($\epsilon$) is initially linear, obeying Hooke’s law:
\[
\sigma \propto \epsilon \quad \Rightarrow \quad \sigma = E\epsilon
\]
where $E$ is Young’s modulus.
However, this linearity holds only up to a certain point called the proportionality limit.
Step 1: Understand stress-strain curve behavior.
The stress-strain curve consists of:
• Linear elastic region (Hooke’s law valid)
• Non-linear elastic region
• Plastic deformation region
The first deviation from linearity occurs even before permanent deformation begins.
Step 2: Definition of proportionality limit.
The proportionality limit is defined as:
\[
\text{The maximum stress up to which stress is directly proportional to strain.}
\]
Beyond this point:
\[
\sigma \not\propto \epsilon
\]
but material may still return to original shape.
Step 3: Distinguish from elastic limit.
• Proportionality limit → deviation from linearity begins
• Elastic limit → permanent deformation begins
Thus proportionality limit comes first.
Final Answer:
\[
\boxed{\text{Proportionality limit}}
\]