The volume \( V \) of a sphere is given by the formula:
\[
V = \frac{4}{3} \pi r^3,
\]
and the surface area \( A \) is given by the formula:
\[
A = 4 \pi r^2.
\]
Let the radii of the two spheres be \( r_1 \) and \( r_2 \), and the ratio of their volumes is given as:
\[
\frac{V_1}{V_2} = \frac{125}{27}.
\]
Using the volume formula:
\[
\frac{\frac{4}{3} \pi r_1^3}{\frac{4}{3} \pi r_2^3} = \frac{125}{27} \quad \Rightarrow \quad \frac{r_1^3}{r_2^3} = \frac{125}{27}.
\]
Taking the cube root of both sides:
\[
\frac{r_1}{r_2} = \frac{5}{3}.
\]
Now, the ratio of the surface areas is:
\[
\frac{A_1}{A_2} = \frac{4 \pi r_1^2}{4 \pi r_2^2} = \frac{r_1^2}{r_2^2} = \left( \frac{5}{3} \right)^2 = \frac{25}{9}.
\]
Thus, the ratio of their surface areas is \( \boxed{25 : 9} \).