The age can be calculated using:
t = \(\left(\ln \frac{(^{14}C/^{12}C)_{\text{initial}}}{(^{14}C/^{12}C)_{\text{sample}}}\right) \frac{t_{1/2}}{\ln 2}\)
Given \(\frac{(^{14}C/^{12}C)_{\text{sample}}}{(^{14}C/^{12}C)_{\text{initial}}} = \frac{1}{8}\),
t = \(\ln 8 \times \frac{5730}{\ln 2} = 17190\) years
The problem is about radiocarbon dating. We need to find the age of a wooden sample given that the ratio of \(^{14}\text{C}\) to \(^{12}\text{C}\) in it is \(\frac{1}{8}\) of the atmospheric ratio, and the half-life of \(^{14}\text{C}\) is 5730 years.
Radioactive decay is a first-order process. The age of a sample can be determined using the relationship between the amount of radioactive substance remaining (\(N\)), the initial amount (\(N_0\)), and the number of half-lives (\(n\)) that have passed.
The fraction of the radioactive isotope remaining is given by:
\[ \frac{N}{N_0} = \left(\frac{1}{2}\right)^n \]The total age (\(t\)) of the sample is the number of half-lives (\(n\)) multiplied by the half-life period (\(t_{1/2}\)):
\[ t = n \times t_{1/2} \]For carbon dating, the ratio \(\frac{^{14}\text{C}}{^{12}\text{C}}\) in a sample is proportional to the amount of \(^{14}\text{C}\) (\(N\)), while the atmospheric ratio is proportional to the initial amount (\(N_0\)) at the time of death.
Step 1: Determine the fraction of \(^{14}\text{C}\) remaining in the wood sample.
The ratio of \(\frac{N}{N_0}\) is equal to the ratio of the \((\frac{^{14}\text{C}}{^{12}\text{C}})\) ratio in the sample to that in the atmosphere.
\[ \frac{N}{N_0} = \frac{\left(\frac{^{14}\text{C}}{^{12}\text{C}}\right)_{\text{sample}}}{\left(\frac{^{14}\text{C}}{^{12}\text{C}}\right)_{\text{atmosphere}}} \]It is given that this ratio is \(\frac{1}{8}\).
\[ \frac{N}{N_0} = \frac{1}{8} \]Step 2: Calculate the number of half-lives (\(n\)) that have passed.
We use the radioactive decay formula:
\[ \frac{N}{N_0} = \left(\frac{1}{2}\right)^n \]Substitute the value of \(\frac{N}{N_0}\):
\[ \frac{1}{8} = \left(\frac{1}{2}\right)^n \]Since \(8 = 2^3\), we can rewrite the equation as:
\[ \left(\frac{1}{2}\right)^3 = \left(\frac{1}{2}\right)^n \]By comparing the exponents, we find:
\[ n = 3 \]This means that three half-lives of \(^{14}\text{C}\) have passed.
Step 3: Calculate the age of the wood sample.
The age (\(t\)) is calculated by multiplying the number of half-lives (\(n\)) by the half-life of \(^{14}\text{C}\) (\(t_{1/2}\)).
Given \( t_{1/2} = 5730 \) years.
\[ t = n \times t_{1/2} = 3 \times 5730 \, \text{years} \]Performing the final multiplication:
\[ t = 3 \times 5730 = 17190 \, \text{years} \]The age of the wood sample is 17190 years.
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)

Cobalt chloride when dissolved in water forms pink colored complex $X$ which has octahedral geometry. This solution on treating with cone $HCl$ forms deep blue complex, $\underline{Y}$ which has a $\underline{Z}$ geometry $X, Y$ and $Z$, respectively, are
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,