Let the radius of the sphere be \( r \). The surface area \( S \) and the volume \( V \) of a sphere are given by the formulas:
\[
S = 4\pi r^2 \quad \text{and} \quad V = \frac{4}{3}\pi r^3
\]
Now, we want to find the rate of change of the volume with respect to the surface area. First, we differentiate both expressions with respect to \( r \):
\[
\frac{dV}{dr} = 4\pi r^2 \quad \text{and} \quad \frac{dS}{dr} = 8\pi r
\]
The rate of change of the volume with respect to the surface area is:
\[
\frac{dV}{dS} = \frac{\frac{dV}{dr}}{\frac{dS}{dr}} = \frac{4\pi r^2}{8\pi r} = \frac{1}{2} r
\]
Now, using the formula for the surface area \( S = 4\pi r^2 \), we solve for \( r \):
\[
r = \sqrt{\frac{S}{4\pi}}
\]
Substitute this value of \( r \) into the expression for \( \frac{dV}{dS} \):
\[
\frac{dV}{dS} = \frac{1}{2} \sqrt{\frac{S}{4\pi}} = \frac{1}{4} \sqrt{\frac{S}{\pi}}
\]
Thus, the correct answer is (D).