Concept:
Quantum numbers are used to describe electrons in an atom completely. There are four quantum numbers:
• Principal quantum number (\(n\))
• Angular momentum quantum number (\(l\))
• Magnetic quantum number (\(m\))
• Spin quantum number (\(s\))
Each quantum number provides specific information about the electron.
Step 1: Understand the role of each quantum number.
Principal quantum number (\(n\)):
• Represents energy level
• Represents size of orbital
Angular momentum quantum number (\(l\)):
• Represents shape of orbital
Magnetic quantum number (\(m\)):
• Represents orientation of orbital
Spin quantum number (\(s\)):
• Represents spin direction of electron
Step 2: Identify the quantum number related to shape.
The shape of orbitals such as:
\[
s,\ p,\ d,\ f
\]
is determined by the angular momentum quantum number.
For example:
\[
l=0 \rightarrow s \text{ orbital}
\]
\[
l=1 \rightarrow p \text{ orbital}
\]
\[
l=2 \rightarrow d \text{ orbital}
\]
Hence shape depends on \(l\).
Step 3: Examine the options carefully.
Option (A): Principal quantum number
Determines size and energy level, not shape.
Incorrect.
Option (B): Angular momentum quantum number
Determines orbital shape.
Correct.
Option (C): Magnetic quantum number
Determines orientation.
Incorrect.
Option (D): Spin quantum number
Determines spin direction.
Incorrect.
Step 4: Choose the correct answer.
Therefore, the quantum number explaining shape of orbital is:
\[
\boxed{\text{Angular momentum quantum number}}
\]
Hence,
\[
\boxed{(2)\ \text{Angular momentum quantum number}}
\]