Question:

The pair of elements which do NOT form superoxides in excess oxygen is:

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Smaller cations stabilize oxide more than superoxide.
Updated On: Jun 17, 2026
  • K, Rb
  • Na, K
  • Li, Mg
  • K, Ba
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The Correct Option is C

Solution and Explanation


Step 1: Superoxide formation is favored by large alkali metals (K, Rb, Cs).

Step 2: Lithium forms only oxide (Li$_2$O) due to small size and high lattice energy.

Step 3: Magnesium (alkaline earth metal) forms oxide (MgO), not superoxide.

Step 4: Hence Li and Mg both do NOT form superoxides.

Step 5: Therefore correct pair is Li, Mg.
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