Concept: For inverse tangent functions, the identity \[ \tan^{-1}a+\tan^{-1}b=\tan^{-1}\!\left(\frac{a+b}{1-ab}\right) \] is valid when \(ab<1\), with the principal value lying in \((-\pi/2,\pi/2)\).
Step 1: Apply the identity. Let \[ a=4x,\quad b=6x \] Then, \[ \tan^{-1}(4x)+\tan^{-1}(6x) = \tan^{-1}\!\left(\frac{10x}{1-24x^2}\right) \] Given: \[ \tan^{-1}\!\left(\frac{10x}{1-24x^2}\right)=\frac{\pi}{6} \]
Step 2: Take tangent on both sides. \[ \frac{10x}{1-24x^2}=\tan\frac{\pi}{6}=\frac{1}{\sqrt{3}} \]
Step 3: Solve for \(x\). \[ 10\sqrt{3}\,x=1-24x^2 \] \[ 24x^2+10\sqrt{3}\,x-1=0 \] Solving: \[ x=\frac{-10\sqrt{3}\pm\sqrt{300+96}}{48} =\frac{-10\sqrt{3}\pm\sqrt{396}}{48} =\frac{-10\sqrt{3}\pm6\sqrt{11}}{48} \]
Step 4: Check interval restriction. Given interval: \[ x\in\left[-\frac{1}{2\sqrt{6}},\,\frac{1}{2\sqrt{6}}\right] \] On numerical evaluation:
One root lies within the given interval
The other root lies outside the given interval Hence, only one value of \(x\) satisfies both the equation and the interval condition.
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)