Step 1: Condition for non-trivial solutions:
A homogeneous system of linear equations admits non-trivial solutions if and only if the determinant of its coefficient matrix is zero.
Step 2: Form the coefficient matrix:
The given system has the coefficient matrix
\[
M = \begin{pmatrix} 2 & 3 & a \\ 1 & a & -2 \\ 3 & 1 & 3 \end{pmatrix}.
\]
Thus, for non-trivial solutions, we require
\[
\det(M) = 0.
\]
Step 3: Evaluate the determinant:
Expanding along the first row,
\[
\det(M) = 2 \begin{vmatrix} a & -2 \\ 1 & 3 \end{vmatrix}
- 3 \begin{vmatrix} 1 & -2 \\ 3 & 3 \end{vmatrix}
+ a \begin{vmatrix} 1 & a \\ 3 & 1 \end{vmatrix}.
\]
Simplifying each term,
\[
2(3a + 2) - 3(3 + 6) + a(1 - 3a) = 0,
\]
\[
6a + 4 - 27 + a - 3a^2 = 0,
\]
\[
-3a^2 + 7a - 23 = 0.
\]
Rewriting,
\[
3a^2 - 7a + 23 = 0.
\]
Step 4: Check for real solutions:
To determine the number of real values of $a$, compute the discriminant:
\[
\Delta = (-7)^2 - 4(3)(23) = 49 - 276 = -227.
\]
Since $\Delta<0$, the quadratic equation has no real roots.
Step 5: Conclusion:
Hence, there are no real values of $a$ for which the system has non-trivial solutions.
\[
\boxed{0}
\]