In a face-centered cubic (FCC) structure, the unit cell includes:
- 8 corner atoms, with each atom contributing \( \frac{1}{8} \) to the unit cell.
- 6 face-centered atoms, with each atom contributing \( \frac{1}{2} \) to the unit cell.
Calculating the total atoms per unit cell gives:
\[
8 \times \frac{1}{8} + 6 \times \frac{1}{2} = 1 + 3 = 4
\]
Thus, the correct answer is (d) \( 4 \).