Step 1: Recall the raw materials used in cement manufacture.
The principal raw material for manufacturing cement is limestone, which supplies calcium carbonate (\(\mathrm{CaCO_3}\)).
Step 2: Identify the correct option.
Since limestone is the major constituent used in cement production,
\[
\boxed{\text{Limestone}}
\]
is the correct answer.
Therefore,
\[
\boxed{(B)}
\]
is the correct answer.