Question:

The IUPAC name of the following compound is \[ \mathrm{(CH_3)_3C-C(OH)(CH_3)_2} \]

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In alcohol nomenclature, \[ \boxed{\text{The hydroxyl group gets the lowest possible locant.}} \] Choose the longest chain containing the carbon bonded to \(-\mathrm{OH}\).
Updated On: Jul 15, 2026
  • 2,3,3-trimethylbutan-2-ol
  • 2,2,3-trimethylbutan-3-ol
  • 1,1,2,2-tetramethylpropan-1-ol
  • 2,2,3,3-tetramethylpropan-3-ol
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The Correct Option is A

Solution and Explanation

Step 1: Choose the longest carbon chain containing the \(-\mathrm{OH}\) group. The longest chain has four carbon atoms. Hence, the parent hydrocarbon is \[ \boxed{\text{butane}.} \]

Step 2:
Number the chain. Numbering is done from the end nearer the hydroxyl group. Thus, \[ \boxed{\text{OH at carbon-2}.} \] The methyl substituents are present at \[ 2,\ 3,\ 3. \] Hence the name is \[ \boxed{\text{2,3,3-trimethylbutan-2-ol}.} \] Therefore, \[ \boxed{(A)} \] is the correct answer.
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