Question:

The incorrect statement(s) among (a) - (c) is (are)
(a) W(VI) is more stable than Cr(VI).
(b) In the presence of HCl, permanganate titrations provide satisfactory results.
(c) Some lanthanoid oxides can be used as phosphors.

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Check each statement: higher oxidation states are more stable down a group, and HCl is oxidised by permanganate.
Updated On: Nov 5, 2026
  • (a) and (b) only
  • (a) only
  • (b) only
  • (b) and (c) only
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The Correct Option is C

Solution and Explanation

(a) Down a group in the d-block, higher oxidation states become more stable, so W(VI) is more stable than Cr(VI) (Cr(VI) is a strong oxidant). Statement (a) is correct.
(b) In HCl, \(\mathrm{MnO_4^-}\) oxidises \(\mathrm{Cl^-}\) to \(\mathrm{Cl_2}\), so part of the permanganate is consumed and the titration is not satisfactory (dilute H2SO4 is used instead). Statement (b) is incorrect.
(c) Some lanthanoid oxides (e.g. of Eu, Y) are used as phosphors in colour television screens. Statement (c) is correct.
Only (b) is incorrect.
Answer: (3) (b) only
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