Step 1: Fact.
Enamel is a highly mineralised layer (mainly hydroxyapatite) covering the crown of the tooth.
Step 2: Comparison.
Dentine lies below enamel and is softer; pulp cavity contains nerves and blood vessels; canine is a type of tooth, not a tissue.
Step 3: Conclusion.
Therefore, enamel is the hardest part of the tooth.