Question:

The First law of thermodynamics is mathematically stated as

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Heat In ($Q$) = Internal Energy Gain ($E$) + Work Done ($W$).
  • $dQ=dE-dW$
  • $dE=dW+dQ$
  • $dH=dW+dQ$
  • $dQ=dE+dW$
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The Correct Option is D

Solution and Explanation

Step 1: Concept
The First Law of Thermodynamics is a version of the law of conservation of energy, adapted for thermodynamic systems.

Step 2: Meaning

It states that the total energy supplied to a system as heat is equal to the increase in its internal energy plus the work done by the system.

Step 3: Analysis

Let $dQ$ be heat supplied, $dE$ (or $dU$) be the change in internal energy, and $dW$ be work done by the system. The balance is $dQ = dE + dW$.

Step 4: Conclusion

This mathematical expression represents the standard formulation where energy entering as heat is accounted for by internal change and external work. Final Answer: (D)
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