Step 1: Find the variance of \(X\).
Given,
\[
X\sim B(16,0.25)
\]
which is a binomial distribution with
\[
n=16,\qquad p=0.25
\]
For a binomial distribution, variance is given by
\[
\mathrm{Var}(X)=npq
\]
where
\[
q=1-p
\]
Thus,
\[
q=1-0.25=0.75
\]
Therefore,
\[
\mathrm{Var}(X)=16\times0.25\times0.75
\]
\[
=4\times0.75
\]
\[
=3
\]
Step 2: Find the variance of \(Y\).
Given,
\[
Y\sim P(2)
\]
which is a Poisson distribution with parameter \(\lambda=2\).
For a Poisson distribution,
\[
\mathrm{Var}(Y)=\lambda
\]
Hence,
\[
\mathrm{Var}(Y)=2
\]
Step 3: Find the sum of variances.
\[
\mathrm{Var}(X)+\mathrm{Var}(Y)
\]
\[
=3+2
\]
\[
=5
\]
Step 4: Final conclusion.
Hence, the required sum is
\[
\boxed{5}
\]