For 2 years, the difference between compound interest and simple interest on a principal P at rate r% per annum is given by the standard result: Difference = P x (r/100)^2.
Statement 1 tells us the rate is 5%. Plugging in: 20 = P x (5/100)^2 = P x 0.0025, so P = 20/0.0025 = 8000. This gives a single, definite value for the sum, so statement 1 alone is sufficient.
Statement 2 tells us the simple interest for one year is Rs. 400, which means P x r/100 = 400. This is one equation with two unknowns (P and r), so we cannot isolate P without knowing the rate. Statement 2 alone is not sufficient.
Since statement 1 alone gives a unique answer and statement 2 alone does not, the correct choice is (a).