Crystals are categorized into seven systems based on their unit cell dimensions and the angles between the edges. Orthorhombic Crystal System:
Defined by three mutually perpendicular axes that are all of unequal length.
The axial relationship is: \[ a \neq b \neq c \quad \text{and} \quad \alpha = \beta = \gamma = 90^\circ \]
Examples of materials with orthorhombic structure include sulfur, olivine, and aragonite.
Why the Other Options Are Incorrect:
(A) Cubic: All three axes are equal in length and intersect at 90°. \[ a = b = c \]
(B) Tetragonal: Two axes are equal, third is different, all angles are 90°. \[ a = b \neq c \]
(D) Monoclinic: Axes are unequal, and only two angles are 90°, one is not. \[ a \neq b \neq c; \, \alpha = \gamma = 90^\circ, \, \beta \neq 90^\circ \]
Hence, the correct answer is Orthorhombic, which features three unequal sides and all 90° angles.