To determine the correct order of N-compounds in decreasing order of oxidation states, we need to calculate the oxidation state of nitrogen in each compound provided:
- HNO3: The oxidation state of hydrogen is +1 and oxygen is -2. Let the oxidation state of nitrogen be x.
The formula for calculating oxidation states is:
+1 + x + 3(-2) = 0.
Solving:
x - 5 = 0
Thus, x = +5.
- NO: Oxygen has an oxidation state of -2. Let the oxidation state of nitrogen be x.
The formula is:
x - 2 = 0.
Solving:
x = +2.
- N2: In its elemental form, the oxidation state of nitrogen is 0.
- NH4Cl: Hydrogen is +1 and since there are four hydrogens, it contributes +4. Chlorine is -1.
Let the oxidation state of nitrogen be x.
The formula for calculating oxidation states is:
x + 4(1) - 1 = 0.
Solving:
x + 3 = 0
Thus, x = -3.
Using the calculations above, we can arrange the oxidation states in decreasing order: +5, +2, 0, -3. Therefore, the decreasing order of oxidation states for the compounds is:
HNO3, NO, N2, NH4Cl.
Thus, the correct option is HNO3, NO, N2, NH4Cl.