Question:

The compound or ion which is not aromatic in the following is

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Aromatic compounds obey Huckel's rule: \[ (4n+2)\pi \text{ electrons} \] while systems with \[ 4n\pi \text{ electrons} \] are generally antiaromatic.
Updated On: Jun 15, 2026
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The Correct Option is B

Solution and Explanation

Step 1: Recall the conditions for aromaticity.
A compound is aromatic if it satisfies all the following conditions:
(i) Cyclic structure (ii) Planar structure (iii) Continuous conjugation \[ \text{(iv) } (4n+2)\pi \text{ electrons} \] This is known as Huckel's rule.

Step 2: Analyze option (1) Pyridine.
Pyridine is a six-membered planar ring with alternating double bonds.
It contains
\[ 6\pi \text{ electrons} \] which satisfies Huckel's rule for \(n=1\).
Hence, pyridine is aromatic.

Step 3: Analyze option (2) Cyclopentadienyl cation.
Cyclopentadienyl cation contains a five-membered conjugated ring with only
\[ 4\pi \text{ electrons} \] According to Huckel's rule, systems with \(4n\pi\) electrons are antiaromatic and hence not aromatic.
Thus, cyclopentadienyl cation is not aromatic.

Step 4: Analyze option (3) Anthracene.
Anthracene is a fused aromatic hydrocarbon with continuous conjugation and follows Huckel's rule.
Therefore, anthracene is aromatic.

Step 5: Analyze option (4) Furan.
Furan is a five-membered heterocyclic compound.
One lone pair of oxygen participates in conjugation, giving a total of
\[ 6\pi \text{ electrons} \] Hence, furan is aromatic.

Step 6: Final conclusion.
Therefore, the compound which is not aromatic is
\[ \boxed{\text{Cyclopentadienyl cation}} \]
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