Question:

The catalyst used in the manufacture of polyethylene is a mixture of

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Ziegler–Natta catalyst generally consists of a titanium halide and an organoaluminium compound.
Updated On: Jun 15, 2026
  • Ti, \(\mathrm{Al(CH_3)_3}\)
  • Ti, \(\mathrm{CH_3MgBr}\)
  • \(\mathrm{TiCl_3,\ Si(CH_3)_4}\)
  • \(\mathrm{TiCl_4,\ Al(CH_3)_3}\)
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The Correct Option is D

Solution and Explanation

Step 1: Recall the catalyst used for polyethylene manufacture.
Polyethylene is commonly manufactured using the Ziegler–Natta catalyst.
This catalyst is used for polymerization of ethene to produce polyethylene.

Step 2: Identify the components of Ziegler–Natta catalyst.
The catalyst consists of a transition metal halide and an organoaluminium compound.
A common combination is:
\[ \mathrm{TiCl_4} \] and
\[ \mathrm{Al(CH_3)_3} \]

Step 3: Explain the role of the catalyst.
\(\mathrm{TiCl_4}\) acts as the transition metal catalyst, while \(\mathrm{Al(CH_3)_3}\) acts as a co-catalyst.
This catalyst system helps in controlled polymerization and formation of linear polyethylene.

Step 4: Eliminate incorrect options.
The other combinations are not standard Ziegler–Natta catalyst systems used in polyethylene manufacture.

Step 5: Final conclusion.
Hence, the catalyst mixture used in the manufacture of polyethylene is
\[ \boxed{\mathrm{TiCl_4,\ Al(CH_3)_3}} \]
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