A monoatomic molecule has only 3 translational degrees of freedom (no rotational or vibrational ones).
From the equipartition of energy principle, each degree contributes:
\[
\frac{1}{2} K_B T
\]
So, total average energy:
\[
E = 3 \times \frac{1}{2} K_B T = \frac{3}{2} K_B T
\]