Anomers are a type of stereoisomers that differ in configuration only at the anomeric carbon. The anomeric carbon is the carbonyl carbon in the open-chain form that becomes a stereocenter when the monosaccharide cyclizes to form a cyclic structure.
Looking at the structures:
- Structure I and Structure III are anomers because they differ in the configuration at the anomeric carbon (the carbon that was originally part of the carbonyl group in the open-chain form).
- Structure II is not an anomer of I or III, as it has a different configuration at a different carbon and is not derived from a similar open-chain form.
Therefore, Structures I and III are the two anomers. Thus, the correct answer is (D)