Question:

Statement I : Sodium and Potassium dichromate are used as a primary standard in redox titrations.
Statement II : Phenolphthalein is weakly basic in nature hence it dissociates in acidic medium.

Updated On: Apr 5, 2026
  • Both Statement I and Statement II are correct
  • Statement I is correct but Statement II is incorrect.
  • Statement I is incorrect but Statement II is correct.
  • Both Statement I and Statement II are incorrect
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The Correct Option is D

Solution and Explanation

Concept:
Primary standards must be stable and non-hygroscopic. Indicators like phenolphthalein behave as weak acids, not bases. Step 1: Analyze Statement I. \[ Na_2Cr_2O_7 \text{ is hygroscopic, hence not used as primary standard} \] Statement I is incorrect. Step 2: Analyze Statement II. Phenolphthalein is a weak acid, not a base. Statement II is incorrect. Step 3: Final answer. \[ \boxed{\text{Both statements are incorrect}} \]
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