Sodium phenoxide when heated with \(\mathrm{CO_2}\) under pressure at \(125^\circ\mathrm{C}\) yields a product which on acetylation produces C.
The major product C would be :
The major product C would be :
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The Correct Option is A
Solution and Explanation
Acetylation of the phenolic OH of B with \(\mathrm{Ac_2O}\) gives 2-acetoxybenzoic acid (acetylsalicylic acid, aspirin), C.
This is the structure with \(\mathrm{OCOCH_3}\) and \(\mathrm{COOH}\) on adjacent (ortho) carbons, option (1).
Answer: (1) 2-acetoxybenzoic acid (aspirin): ortho \(\mathrm{OCOCH_3}\) and \(\mathrm{COOH}\)
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