A temperature difference can generate e.m.f. in some materials. Let $ S $ be the e.m.f. produced per unit temperature difference between the ends of a wire, $ \sigma $ the electrical conductivity and $ \kappa $ the thermal conductivity of the material of the wire. Taking $ M, L, T, I $ and $ K $ as dimensions of mass, length, time, current and temperature, respectively, the dimensional formula of the quantity $ Z = \frac{S^2 \sigma}{\kappa} $ is:
An ideal monatomic gas of $ n $ moles is taken through a cycle $ WXYZW $ consisting of consecutive adiabatic and isobaric quasi-static processes, as shown in the schematic $ V-T $ diagram. The volume of the gas at $ W, X $ and $ Y $ points are, $ 64 \, \text{cm}^3 $, $ 125 \, \text{cm}^3 $ and $ 250 \, \text{cm}^3 $, respectively. If the absolute temperature of the gas $ T_W $ at the point $ W $ is such that $ n R T_W = 1 \, J $ ($ R $ is the universal gas constant), then the amount of heat absorbed (in J) by the gas along the path $ XY $ is 
A pendulum consists of a bob of mass $m =01\, kg$ and a massless inextensible string of length $L =10 \,m $ It is suspended from a fixed point at height $H =09 \,m$ above a frictionless horizontal floor Initially, the bob of the pendulum is lying on the floor at rest vertically below the point of suspension A horizontal impulse $P =02\, kg - m / s$ is imparted to the bob at some instant After the bob slides for some distance, the string becomes taut and the bob lifts off the floor The magnitude of the angular momentum of the pendulum about the point of suspension just before the bob lifts off is $J \,kg - m ^{2} / s$ The kinetic energy of the pendulum just after the lift-off is $K$ Joules The value of $J$ is ______
List-I | List-II | ||
|---|---|---|---|
| I | A and B are moving on a horizontal circle of radius 1 m with uniform angular speed ω = 1 rad s–1. The initial angular positions of A and B at time t = 0 are θ = 0 and θ = \(\frac{\pi}{2}\), respectively. ![]() | P | \(\frac{\sqrt{3}+1}{2}\) |
| II | Projectiles A and B are fired (in the same vertical plane) at t = 0 and t = 0.1 s respectively,with the same speed \(v=\frac{5\pi}{\sqrt{2}}\)m s–1 and at 45° from the horizontal plane. The initial separation between A and B is large enough so that they do not collide,(g =10 m s -2 ). | Q | \(\frac{\sqrt{3}-1}{\sqrt{2}}\) |
| III | Two harmonic oscillators A and B moving in the x direction according to \(x_A = x_0 sin\frac{t}{t_0}\) and \(x_B=x_0 sin(\frac{t}{t_0}+\frac{\pi}{2})\) respectively, starting from t = 0. Take x0 = 1 m, t0 = 1 s. | R | \(\sqrt{10}\) |
| IV | Particle A is rotating in a horizontal circular path of radius 1 m on the xy plane, with constant angular speed ω = 1 rad s–1. Particle B is moving up at a constant speed 3 ms–1 in the vertical direction as shown in the figure. (Ignore gravity) | S | \(\sqrt{2}\) |
| T | \(\sqrt{25\pi^{2}+1}\) | ||

Monocyclic compounds $ P, Q, R $ and $ S $ are the major products formed in the reaction sequences given below.
The product having the highest number of unsaturated carbon atom(s) is:
For the reaction sequence given below, the correct statement(s) is(are): 
Consider a reaction $ A + R \rightarrow Product $. The rate of this reaction is measured to be $ k[A][R] $. At the start of the reaction, the concentration of $ R $, $[R]_0$, is 10-times the concentration of $ A $, $[A]_0$. The reaction can be considered to be a pseudo first order reaction with assumption that $ k[R] = k' $ is constant. Due to this assumption, the relative error (in %) in the rate when this reaction is 40% complete, is ____. [$k$ and $k'$ represent corresponding rate constants]