Question:

\(\mathrm{Cu^{2+}}\) salt reacts with potassium iodide to give

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Cu(II) oxidises iodide to iodine and is itself reduced to insoluble Cu(I) iodide.
Updated On: Nov 4, 2026
  • \(\mathrm{Cu_2I_2}\)
  • \(\mathrm{Cu_2I_3}\)
  • \(\mathrm{CuI}\)
  • \(\mathrm{Cu(I_3)_2}\)
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The Correct Option is C

Solution and Explanation

\(\mathrm{Cu^{2+}}\) oxidises \(\mathrm{I^-}\) to \(\mathrm{I_2}\) and is itself reduced to \(\mathrm{Cu^+}\), which precipitates with iodide as white CuI:
\(\mathrm{2Cu^{2+} + 4I^- \rightarrow 2CuI\downarrow + I_2}\)
Options (2) and (4) are not stable compounds because \(\mathrm{Cu^{2+}}\) cannot form \(\mathrm{CuI_2}\) (it oxidises iodide). Option (1) \(\mathrm{Cu_2I_2}\) is only a non-simplest way of writing CuI; the expected answer is the formula CuI, option (3).
Answer: (3) \(\mathrm{CuI}\)
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