| Column-I | Column-II | ||
| P | N2O5 | (i) | N–N bond |
| Q | N2O | (ii) | N–O–N bond |
| R | N2O4 | (iii) | N=N / N≡N bond |
| S | NO2 | (iv) | N=O bond |
P – (ii), Q – (iii), R – (i), S – (iv)
Method used for separation of mixture of products (B and C) obtained in the following reaction is: 
A substance 'X' (1.5 g) dissolved in 150 g of a solvent 'Y' (molar mass = 300 g mol$^{-1}$) led to an elevation of the boiling point by 0.5 K. The relative lowering in the vapour pressure of the solvent 'Y' is $____________ \(\times 10^{-2}\). (nearest integer)
[Given : $K_{b}$ of the solvent = 5.0 K kg mol$^{-1}$]
Assume the solution to be dilute and no association or dissociation of X takes place in solution.