Step 1: Goniophotometer.
This instrument measures the luminous flux of directed light sources, checking how light intensity is distributed at different angles.
\[
P \Rightarrow 2
\]
Step 2: Pyrheliometer.
It directly measures solar irradiance (beam radiation) from the sun.
\[
Q \Rightarrow 3
\]
Step 3: Spectrophotometer.
This device measures electromagnetic energy at specific wavelengths of light, analyzing how much light is absorbed or transmitted at each wavelength.
\[
R \Rightarrow 1
\]
Step 4: Forward-Looking Infrared Camera (FLIR).
This camera is used for thermal imaging → measurement of temperature.
\[
S \Rightarrow 4
\]
\[
\boxed{P-2, \ Q-3, \ R-1, \ S-4}
\]
Using the following values of thermal conductance, surface conductance, and thermal resistance, the U value across the given wall cross-section is \(\underline{\hspace{1cm}}\) W/m\(^2\)°C (round off to 2 decimal places). 
