Step 1: Identify the first trophic level.
Producers occupy first trophic level.
\[
\text{Grass} \rightarrow \text{First trophic level}
\]
Step 2: Identify primary consumer.
Grasshopper feeds on plants.
\[
\text{Grasshopper} \rightarrow \text{Second trophic level}
\]
Step 3: Identify secondary consumer.
Snake feeds on herbivores.
\[
\text{Snake} \rightarrow \text{Third trophic level}
\]
Step 4: Identify higher consumer.
Vulture occupies higher trophic position.
\[
\text{Vulture} \rightarrow \text{Fourth trophic level}
\]
Thus,
\[
A-I,\; B-V,\; C-II,\; D-III
\]
\[
\boxed{\text{Option (D)}}
\]