Step 1: Recall the definitions.
\[
\boxed{
\begin{aligned}
\text{Apoenzyme} &\rightarrow \text{Protein part of an enzyme}
\text{Coenzyme} &\rightarrow \text{Organic non-protein cofactor}
\text{Holoenzyme} &\rightarrow \text{Apoenzyme + Cofactor}
\text{Active site} &\rightarrow \text{Substrate-binding region}
\end{aligned}
}
\]
Step 2: Match List-I with List-II.
Thus,
\[
\boxed{
A-\mathrm{II},\;
B-\mathrm{I},\;
C-\mathrm{III},\;
D-\mathrm{IV}
}
\]
Therefore,
\[
\boxed{(A)}
\]
is the correct answer.