Step 1: Analyze each component.
- P. Sympathetic – (iv) Fight-or-flight system: Mobilizes the body under stress.
- Q. Parasympathetic – (iii) Maintaining body functions under normal conditions: Supports “rest and digest.”
- R. Afferent – (ii) Carrying messages from senses to Central Nervous System: Transmits sensory information.
- S. Efferent – (i) Carrying messages from Central Nervous System to muscles and glands: Sends motor commands.
Thus, the correct matching is: \[ \boxed{{P–iv; Q–iii; R–ii; S–i}} \]