Step 1: Understanding the Concept:
The task is to match words from List I with their synonymous terms or definitions in List II.
Step 2: Detailed Explanation:
1. Amicable: Refers to a relationship or spirit of friendliness. Its synonym is Harmonious (IV).
2. Penuary (Penury): Refers to the state of extreme poverty. Its synonym is Destitution (I).
3. Imposture: Refers to the practice of deceiving others by pretending to be someone else. Its synonym is Deception (II).
4. Solicitous: Characterized by showing interest, care, or concern; often manifests as being Anxious (III) about someone's well-being.
Step 3: Final Answer:
The correct matching is A-IV, B-I, C-II, D-III. This corresponds to Option (4).