Question:

Match List - I with List - II.

Choose the correct answer from the options given below :

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Diazonium salt + \(\mathrm{Cu_2Cl_2}\) is Sandmeyer; diazonium salt + Cu/HCl is Gattermann; alkyl halide + Na/ether is Wurtz; aryl halide + Na/ether is Fittig.
Updated On: Nov 4, 2026
  • (a) \(\to\) (ii), (b) \(\to\) (iv), (c) \(\to\) (i), (d) \(\to\) (iii)
  • (a) \(\to\) (iii), (b) \(\to\) (iv), (c) \(\to\) (i), (d) \(\to\) (ii)
  • (a) \(\to\) (iii), (b) \(\to\) (i), (c) \(\to\) (iv), (d) \(\to\) (ii)
  • (a) \(\to\) (ii), (b) \(\to\) (i), (c) \(\to\) (iv), (d) \(\to\) (iii)
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The Correct Option is A

Solution and Explanation

(a) Benzenediazonium chloride with \(\mathrm{Cu_2Cl_2}\) gives chlorobenzene + \(\mathrm{N_2}\): Sandmeyer reaction, (ii).
(b) Benzenediazonium chloride with Cu/HCl gives chlorobenzene + \(\mathrm{N_2}\): Gattermann reaction, (iv).
(c) \(\mathrm{2CH_3CH_2Cl + 2Na \to C_2H_5-C_2H_5 + 2NaCl}\) (coupling of alkyl halides in dry ether): Wurtz reaction, (i).
(d) \(\mathrm{2C_6H_5Cl + 2Na \to C_6H_5-C_6H_5 + 2NaCl}\) (coupling of aryl halides): Fittig reaction, (iii).
Thus (a)-(ii), (b)-(iv), (c)-(i), (d)-(iii).
Answer: (1) (a) \(\to\) (ii), (b) \(\to\) (iv), (c) \(\to\) (i), (d) \(\to\) (iii)
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