From the given equation:
\[ \vec{a} \times (\vec{b} + \vec{c}) + \vec{b} \times \vec{c} = \hat{i} + 8\hat{j} + 13\hat{k}. \]
Expanding using vector algebra:
\[ \vec{a} \times \vec{b} + \vec{a} \times \vec{c} + \vec{b} \times \vec{c} = \hat{i} + 8\hat{j} + 13\hat{k}. \]
It is given:
\[ \vec{a} \times \vec{b} = \hat{i} + 8\hat{j} + 13\hat{k}. \]
So:
\[ \vec{a} \times \vec{c} + \vec{b} \times \vec{c} = \vec{0}. \]
Expanding further:
\[ \vec{b} \times \vec{c} = -\vec{a} \times \vec{c}. \]
Using \( \vec{a} \cdot \vec{c} = 13 \), compute:
\[ \vec{b} \cdot \vec{c} = -\left[\vec{a} \cdot (\hat{i} + 8\hat{j} + 13\hat{k})\right] = -22. \]
From the determinant of \( \vec{b} \cdot \vec{c} \):
\[ 24 - \vec{b} \cdot \vec{c} = 46. \]
We are given two vectors \( \vec{a} = 2\hat{i} - 3\hat{j} + 4\hat{k} \), \( \vec{b} = 3\hat{i} + 4\hat{j} - 5\hat{k} \), and a vector \( \vec{c} \). We are provided with a vector equation \( \vec{a} \times (\vec{b} + \vec{c}) + \vec{b} \times \vec{c} = \hat{i} + 8\hat{j} + 13\hat{k} \) and a scalar condition \( \vec{a} \cdot \vec{c} = 13 \). The goal is to find the value of the expression \( (24 - \vec{b} \cdot \vec{c}) \).
The solution involves the use of fundamental properties of vector algebra:
1. Distributive Property of Vector Cross Product: The cross product is distributive over vector addition.
\[ \vec{u} \times (\vec{v} + \vec{w}) = \vec{u} \times \vec{v} + \vec{u} \times \vec{w} \] \[ (\vec{u} + \vec{v}) \times \vec{w} = \vec{u} \times \vec{w} + \vec{v} \times \vec{w} \]2. Vector Triple Product (BAC-CAB Rule): The expansion of a triple cross product is given by:
\[ \vec{u} \times (\vec{v} \times \vec{w}) = (\vec{u} \cdot \vec{w})\vec{v} - (\vec{u} \cdot \vec{v})\vec{w} \]3. Standard methods for calculating the scalar (dot) and vector (cross) products of vectors in component form.
Step 1: Simplify the given vector equation.
We start with the equation \( \vec{a} \times (\vec{b} + \vec{c}) + \vec{b} \times \vec{c} = \hat{i} + 8\hat{j} + 13\hat{k} \).
Using the distributive property on the first term:
\[ (\vec{a} \times \vec{b} + \vec{a} \times \vec{c}) + \vec{b} \times \vec{c} = \hat{i} + 8\hat{j} + 13\hat{k} \]Group the terms involving \( \vec{c} \):
\[ \vec{a} \times \vec{b} + (\vec{a} \times \vec{c} + \vec{b} \times \vec{c}) = \hat{i} + 8\hat{j} + 13\hat{k} \]Using the distributive property again:
\[ \vec{a} \times \vec{b} + (\vec{a} + \vec{b}) \times \vec{c} = \hat{i} + 8\hat{j} + 13\hat{k} \]Isolate the term containing \( \vec{c} \):
\[ (\vec{a} + \vec{b}) \times \vec{c} = (\hat{i} + 8\hat{j} + 13\hat{k}) - (\vec{a} \times \vec{b}) \]Step 2: Calculate the constant vectors \( \vec{a} \times \vec{b} \) and \( \vec{a} + \vec{b} \).
\[ \vec{a} + \vec{b} = (2+3)\hat{i} + (-3+4)\hat{j} + (4-5)\hat{k} = 5\hat{i} + \hat{j} - \hat{k} \] \[ \vec{a} \times \vec{b} = \begin{vmatrix} \hat{i} & \hat{j} & \hat{k} \\ 2 & -3 & 4 \\ 3 & 4 & -5 \end{vmatrix} = \hat{i}(15 - 16) - \hat{j}(-10 - 12) + \hat{k}(8 - (-9)) = -\hat{i} + 22\hat{j} + 17\hat{k} \]Step 3: Substitute these values into the simplified equation from Step 1.
Let \( \vec{V} = (\hat{i} + 8\hat{j} + 13\hat{k}) - (\vec{a} \times \vec{b}) \).
\[ \vec{V} = (\hat{i} + 8\hat{j} + 13\hat{k}) - (-\hat{i} + 22\hat{j} + 17\hat{k}) = 2\hat{i} - 14\hat{j} - 4\hat{k} \]The simplified equation becomes: \( (\vec{a} + \vec{b}) \times \vec{c} = \vec{V} \).
Step 4: Use the vector triple product to find an expression for \( \vec{c} \).
Take the cross product of the equation with \( \vec{a} \):
\[ \vec{a} \times ((\vec{a} + \vec{b}) \times \vec{c}) = \vec{a} \times \vec{V} \]Applying the BAC-CAB rule to the left side:
\[ (\vec{a} \cdot \vec{c})(\vec{a} + \vec{b}) - (\vec{a} \cdot (\vec{a} + \vec{b}))\vec{c} = \vec{a} \times \vec{V} \]Step 5: Calculate the necessary scalar and vector products.
We are given \( \vec{a} \cdot \vec{c} = 13 \).
Calculate \( \vec{a} \cdot (\vec{a} + \vec{b}) \):
\[ \vec{a} \cdot (\vec{a} + \vec{b}) = (2\hat{i} - 3\hat{j} + 4\hat{k}) \cdot (5\hat{i} + \hat{j} - \hat{k}) = (2)(5) + (-3)(1) + (4)(-1) = 10 - 3 - 4 = 3 \]Calculate \( \vec{a} \times \vec{V} \):
\[ \vec{a} \times \vec{V} = \begin{vmatrix} \hat{i} & \hat{j} & \hat{k} \\ 2 & -3 & 4 \\ 2 & -14 & -4 \end{vmatrix} = \hat{i}(12 - (-56)) - \hat{j}(-8 - 8) + \hat{k}(-28 - (-6)) = 68\hat{i} + 16\hat{j} - 22\hat{k} \]Step 6: Substitute these values back into the equation from Step 4 to solve for \( \vec{c} \).
\[ (13)(\vec{a} + \vec{b}) - (3)\vec{c} = \vec{a} \times \vec{V} \] \[ 13(5\hat{i} + \hat{j} - \hat{k}) - 3\vec{c} = 68\hat{i} + 16\hat{j} - 22\hat{k} \] \[ 65\hat{i} + 13\hat{j} - 13\hat{k} - 3\vec{c} = 68\hat{i} + 16\hat{j} - 22\hat{k} \]Rearranging to solve for \( \vec{c} \):
\[ -3\vec{c} = (68 - 65)\hat{i} + (16 - 13)\hat{j} + (-22 + 13)\hat{k} \] \[ -3\vec{c} = 3\hat{i} + 3\hat{j} - 9\hat{k} \] \[ \vec{c} = -\hat{i} - \hat{j} + 3\hat{k} \]Step 7: Calculate the scalar product \( \vec{b} \cdot \vec{c} \).
We have \( \vec{b} = 3\hat{i} + 4\hat{j} - 5\hat{k} \) and \( \vec{c} = -\hat{i} - \hat{j} + 3\hat{k} \).
\[ \vec{b} \cdot \vec{c} = (3)(-1) + (4)(-1) + (-5)(3) \] \[ \vec{b} \cdot \vec{c} = -3 - 4 - 15 = -22 \]Step 8: Compute the final required value.
\[ 24 - (\vec{b} \cdot \vec{c}) = 24 - (-22) = 24 + 22 = 46 \]The value of \( (24 - \vec{b} \cdot \vec{c}) \) is 46.
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,