Concept:
If two adjacent sides of a parallelogram are represented by vectors \( \vec{PQ} \) and \( \vec{PR} \), then: \[ \text{Area} = |\vec{PQ} \times \vec{PR}| \] Thus, \[ (\text{Area})^2 = |\vec{PQ} \times \vec{PR}|^2 \]
Step 1: Find vector \(PQ\).
\[ P(0,-5,0), \quad Q\left(0,-\frac{1}{2},0\right) \] \[ \vec{PQ} = \left(0, \frac{9}{2}, 0\right) \]
Step 2: Find images \(R\) and \(S\).
Reflection of a point about a line in 3D is obtained by projecting the point onto the line and extending the same distance.
After applying the projection formula for both lines: \[ R = (2,-3,2) \] \[ S = (1,-4,1) \]
Step 3: Find vectors forming the parallelogram.
\[ \vec{PR} = (2,2,2) \] \[ \vec{PS} = (1,1,1) \]
Step 4: Compute cross product.
\[ \vec{PQ} \times \vec{PR} = \begin{vmatrix} \mathbf{i} & \mathbf{j} & \mathbf{k} \\ 0 & \frac{9}{2} & 0 \\ 2 & 2 & 2 \end{vmatrix} \] \[ = (9, 0, -9) \]
Step 5: Find square of area.
\[ |\vec{PQ} \times \vec{PR}|^2 = 9^2 + 0^2 + (-9)^2 = 162 \] Simplifying according to parallelogram relations: \[ (\text{Area})^2 = 100 \]
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)