The binomial expansion of \( (a + b)^{12} \) gives terms of the form: \[ T_r = \binom{12}{r} a^{12-r} b^r \] We are given that the coefficients of three consecutive terms \( T_r \), \( T_{r+1} \), and \( T_{r+2} \) form a geometric progression (G.P.).
Step 2: Form the Ratio EquationThe condition for G.P. gives: \[ \frac{T_{r+1}}{T_r} = \frac{T_{r+2}}{T_{r+1}} \] Substituting the binomial coefficients: \[ \frac{\binom{12}{r+1}}{\binom{12}{r}} = \frac{\binom{12}{r+2}}{\binom{12}{r+1}} \] This simplifies to: \[ \frac{12-r}{r+1} = \frac{12-r-1}{r+2} \]
Step 3: Solve the Quadratic EquationExpanding and simplifying: \[ 13 - r = 12r - r^2 \] Rearranging, \[ 13 = r(12 - r) \] This simplifies to: \[ 13 = 12r - r^2 \] Solving the quadratic equation reveals no valid values for \( r \), so \( p = 0 \).
Step 4: Calculate the Sum of Rational TermsFor the expansion of \( \left( 4\sqrt{3} + 3\sqrt{4} \right)^{12} \), the general term is: \[ T_r = \binom{12}{r} (4\sqrt{3})^{12-r} (3\sqrt{4})^r \] The rational terms occur when the exponents of the square roots are even. Calculating the sum of these rational terms: \[ q = 27 + 256 = 283 \] Thus, \[ p + q = 0 + 283 = 283 \]
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,