The determinant is given by:
\[ D = \left| \begin{matrix} 1 & 1 & \sqrt{3} \\ -1 & \tan \theta & \sqrt{7} \\ 1 & 1 & \tan \theta \end{matrix} \right| = 0 \]
Simplifying the determinant expression: \[ \tan^2 \theta - (\sqrt{3} - 1) - \sqrt{3} = 0 \]
Solving for \( \tan \theta \): \[ \tan \theta = \sqrt{3}, -1 \]
Therefore, the possible values for \( \theta \) are: \[ \theta = \left\{ \frac{\pi}{3}, -\frac{2\pi}{3}, -\frac{\pi}{4}, \frac{3\pi}{4} \right\} \]
Now, calculating the sum of angles: \[ \frac{120}{\pi} \left( \sum \theta \right) = \frac{120}{\pi} \times \frac{\pi}{6} = 20 \quad (\text{Option 2}) \]
A substance 'X' (1.5 g) dissolved in 150 g of a solvent 'Y' (molar mass = 300 g mol$^{-1}$) led to an elevation of the boiling point by 0.5 K. The relative lowering in the vapour pressure of the solvent 'Y' is $____________ \(\times 10^{-2}\). (nearest integer)
[Given : $K_{b}$ of the solvent = 5.0 K kg mol$^{-1}$]
Assume the solution to be dilute and no association or dissociation of X takes place in solution.