Step 1: General form of terms in a geometric progression. In a geometric progression (GP), the general term is given by: \[ a_n = a_1 r^{n-1}, \] where \( a_1 \) is the first term and \( r \) is the common ratio.
Step 2: Using the given conditions. We are given the product of the fourth and sixth terms: \[ a_4 \cdot a_6 = 9. \] Using the general form of the terms: \[ a_4 = a_1 r^3 \quad \text{and} \quad a_6 = a_1 r^5, \] so: \[ a_1 r^3 \cdot a_1 r^5 = 9 \quad \Rightarrow \quad a_1^2 r^8 = 9. \quad \cdots (1) \] We are also given the sum of the fifth and seventh terms: \[ a_5 + a_7 = 24. \] Using the general form of the terms: \[ a_5 = a_1 r^4 \quad \text{and} \quad a_7 = a_1 r^6, \] so: \[ a_1 r^4 + a_1 r^6 = 24 \quad \Rightarrow \quad a_1 r^4(1 + r^2) = 24. \quad \cdots (2) \]
Step 3: Solving equations (1) and (2). From equation (1): \[ a_1^2 r^8 = 9 \quad \Rightarrow \quad a_1^2 = \frac{9}{r^8}. \quad \cdots (3) \] From equation (2): \[ a_1 r^4 (1 + r^2) = 24 \quad \Rightarrow \quad a_1 = \frac{24}{r^4(1 + r^2)}. \quad \cdots (4) \] Substitute equation (4) into equation (3): \[ \left( \frac{24}{r^4(1 + r^2)} \right)^2 r^8 = 9 \quad \Rightarrow \quad \frac{576 r^8}{r^8 (1 + r^2)^2} = 9 \quad \Rightarrow \quad \frac{576}{(1 + r^2)^2} = 9. \] Solving this: \[ (1 + r^2)^2 = \frac{576}{9} = 64 \quad \Rightarrow \quad 1 + r^2 = 8 \quad \Rightarrow \quad r^2 = 7. \]
Step 4: Finding \( a_1 \) and solving for the desired expression. From equation (3), substitute \( r^2 = 7 \) into the equation: \[ a_1^2 = \frac{9}{r^8} = \frac{9}{(7)^4} = \frac{9}{2401} \quad \Rightarrow \quad a_1 = \frac{3}{49}. \] Now, we compute the expression \( a_1a_9 + a_2a_8 + a_3a_7 + a_4a_6 \). The terms are: \[ a_9 = a_1 r^8, \quad a_8 = a_1 r^7, \quad a_7 = a_1 r^6, \quad a_6 = a_1 r^5, \] so: \[ a_1a_9 = a_1^2 r^8, \quad a_2a_8 = a_1^2 r^6, \quad a_3a_7 = a_1^2 r^4, \quad a_4a_6 = a_1^2 r^8. \] Summing these terms: \[ a_1a_9 + a_2a_8 + a_3a_7 + a_4a_6 = a_1^2 (r^8 + r^6 + r^4 + r^8). \] Simplifying: \[ = a_1^2 (2r^8 + r^6 + r^4). \] Substitute \( r^2 = 7 \): \[ r^4 = 49, \quad r^6 = 343, \quad r^8 = 2401. \] Thus: \[ a_1a_9 + a_2a_8 + a_3a_7 + a_4a_6 = a_1^2 (2 \times 2401 + 343 + 49) = a_1^2 (4802 + 343 + 49) = a_1^2 \times 5194. \] Finally: \[ a_1a_9 + a_2a_8 + a_3a_7 + a_4a_6 = \frac{9}{2401} \times 5194 = 60. \]
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,