We are given:
\( \vec{a} = \hat{i} + 2\hat{j} + 3\hat{k}, \quad \vec{b} = \hat{i} + \hat{j} - \hat{k}. \)
Let \( \theta \) be the angle between \( \vec{b} \) and \( \vec{a} \times \vec{c} \). The magnitude of their product is:
\( |\vec{b} \cdot (\vec{a} \times \vec{c})| \sin \theta = 3\sqrt{14}. \)
The magnitude of the dot product is:
\( |\vec{b} \cdot (\vec{a} \times \vec{c})| \cos \theta = 27. \)
Divide the equations to find \( \sin \theta \):
\( \sin \theta = \frac{\sqrt{14}}{\sqrt{95}}. \)
From the given relationships:
\( |\vec{b} \times (\vec{a} \times \vec{c})| = 3\sqrt{95}. \)
From the magnitude relationship:
\( |\vec{a} \times \vec{c}| = \sqrt{3 \times \sqrt{95}}. \)
\( |\vec{a} \times \vec{c}|^2 = 3 \times 95 = 285. \)
\( |\vec{a} \times \vec{c}| = \sqrt{285}. \)
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)