Concept:
A fundamental property of a real symmetric matrix is that eigenvectors corresponding to distinct eigenvalues are mutually orthogonal.
If
\[
AX_1=\lambda_1X_1,\qquad
AX_2=\lambda_2X_2,
\]
where \(\lambda_1\neq\lambda_2\), then
\[
X_1^TX_2=0.
\]
Hence, the dot product of the two eigenvectors is zero.
Step 1: Write the given eigenvalue equations.
Since \(X_1\) and \(X_2\) are eigenvectors of the symmetric matrix \(A\),
\[
AX_1=\lambda_1X_1,
\]
and
\[
AX_2=\lambda_2X_2.
\]
Step 2: Premultiply the second equation by \(X_1^T\).
We obtain
\[
X_1^TAX_2=\lambda_2X_1^TX_2.
\]
Since \(A\) is symmetric,
\[
A^T=A.
\]
Also,
\[
X_1^TAX_2=(AX_1)^TX_2.
\]
Using
\[
AX_1=\lambda_1X_1,
\]
we get
\[
X_1^TAX_2
=\lambda_1X_1^TX_2.
\]
Therefore,
\[
\lambda_1X_1^TX_2
=
\lambda_2X_1^TX_2.
\]
Step 3: Use the fact that the eigenvalues are distinct.
Thus,
\[
(\lambda_1-\lambda_2)X_1^TX_2=0.
\]
Since
\[
\lambda_1\neq\lambda_2,
\]
it follows that
\[
X_1^TX_2=0.
\]
Hence,
\[
X_2^TX_1=0.
\]
Therefore, the correct option is
\[
\boxed{(D)\;X_2^TX_1=0.}
\]