Step 1: Condition for coplanarity. For three vectors \( \mathbf{AB}, \mathbf{AC}, \mathbf{AD} \) to be coplanar, the scalar triple product must be zero: \[ \mathbf{AB} \cdot (\mathbf{AC} \times \mathbf{AD}) = 0. \]
Step 2: Expressing \( \mathbf{AB}, \mathbf{AC}, \mathbf{AD} \) in terms of \( \mathbf{a}, \mathbf{b}, \mathbf{c} \). The position vector of point \( A \) is: \[ \mathbf{A} = \mathbf{a} - \mathbf{b} + \mathbf{c}. \] The position vectors of points \( B, C, D \) are given as: \[ \mathbf{B} = \lambda \mathbf{a} - 3 \mathbf{b} + 4 \mathbf{c}, \quad \mathbf{C} = -\mathbf{a} + 2 \mathbf{b} - 3 \mathbf{c}, \quad \mathbf{D} = 2 \mathbf{a} - 4 \mathbf{b} + 6 \mathbf{c}. \] Now, the vectors \( \mathbf{AB}, \mathbf{AC}, \mathbf{AD} \) are given by: \[ \mathbf{AB} = \mathbf{B} - \mathbf{A} = (\lambda \mathbf{a} - 3 \mathbf{b} + 4 \mathbf{c}) - (\mathbf{a} - \mathbf{b} + \mathbf{c}) = (\lambda - 1) \mathbf{a} - 2 \mathbf{b} + 3 \mathbf{c}, \] \[ \mathbf{AC} = \mathbf{C} - \mathbf{A} = (-\mathbf{a} + 2 \mathbf{b} - 3 \mathbf{c}) - (\mathbf{a} - \mathbf{b} + \mathbf{c}) = -2 \mathbf{a} + 3 \mathbf{b} - 4 \mathbf{c}, \] \[ \mathbf{AD} = \mathbf{D} - \mathbf{A} = (2 \mathbf{a} - 4 \mathbf{b} + 6 \mathbf{c}) - (\mathbf{a} - \mathbf{b} + \mathbf{c}) = \mathbf{a} - 3 \mathbf{b} + 5 \mathbf{c}. \]
Step 3: Computing the scalar triple product. Now, we compute the scalar triple product: \[ \mathbf{AB} \cdot (\mathbf{AC} \times \mathbf{AD}) = 0. \] Substitute the expressions for \( \mathbf{AB}, \mathbf{AC}, \mathbf{AD} \): \[ \left( (\lambda - 1) \mathbf{a} - 2 \mathbf{b} + 3 \mathbf{c} \right) \cdot \left( (-2) \mathbf{a} + 3 \mathbf{b} - 4 \mathbf{c} \right) \times \left( \mathbf{a} - 3 \mathbf{b} + 5 \mathbf{c} \right) = 0. \]
Step 4: Expanding and solving for \( \lambda \). After performing the necessary vector cross and dot products, the equation simplifies to: \[ \lambda = 2. \]
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,