Step 1: Find the value of $\alpha$.
The YZ-plane (where $x=0$) divides the line segment joining $A(\alpha,4,7)$ and $B(3,\beta,8)$ in the ratio $m:n=2:3$.
Using the section formula for the x-coordinate, the point of division has an x-coordinate of 0.
\[
x = \frac{m x_B + n x_A}{m+n} = 0 \implies \frac{2(3) + 3(\alpha)}{2+3} = 0.
\]
\[
6 + 3\alpha = 0 \implies 3\alpha = -6 \implies \alpha = -2.
\]
Step 2: Find the value of $\beta$.
The ZX-plane (where $y=0$) divides the same segment in the ratio $m:n=4:5$.
Using the section formula for the y-coordinate, the point of division has a y-coordinate of 0.
\[
y = \frac{m y_B + n y_A}{m+n} = 0 \implies \frac{4(\beta) + 5(4)}{4+5} = 0.
\]
\[
4\beta + 20 = 0 \implies 4\beta = -20 \implies \beta = -5.
\]
Step 3: Apply the external section formula.
We need to find the point C that divides the segment AB externally in the ratio $\alpha:\beta$, which is $-2:-5$ or $2:5$.
The coordinates are $A(-2,4,7)$ and $B(3,-5,8)$. The ratio is $m:n=2:5$.
The formula for external division is $C = \left(\frac{mx_2 - nx_1}{m-n}, \frac{my_2 - ny_1}{m-n}, \frac{mz_2 - nz_1}{m-n}\right)$.
\[
x_C = \frac{2(3) - 5(-2)}{2-5} = \frac{6+10}{-3} = -\frac{16}{3}.
\]
\[
y_C = \frac{2(-5) - 5(4)}{2-5} = \frac{-10-20}{-3} = \frac{-30}{-3} = 10.
\]
\[
z_C = \frac{2(8) - 5(7)}{2-5} = \frac{16-35}{-3} = \frac{-19}{-3} = \frac{19}{3}.
\]
The coordinates of point C are $(-\frac{16}{3}, 10, \frac{19}{3})$.